Grain Refinement and Hall-Petch Strengthening of Magnesium Alloy Via Alloying and Hot Extrusion

Document Type : Research Paper

Authors

1 University of Tehran

2 College of Engineering - University of Tehran

Abstract

The effects of the addition of Al, Zn and Mn along with the application of the hot extrusion process on the microstructural refinement and enhancement of mechanical properties of magnesium alloy were studied. Based on the Mg-2Al alloy, it was found that the addition of 0.5 wt% Zn to form Mg-2Al-0.5Zn alloy or 0.5 wt% Mn to form Mg-2Al-0.5Mn alloy is the effective way for grain refinement of α-Mg in the as-cast state. Moreover, further remarkable refinement of grain size can be achieved by the extrusion process in such a way that the average grain size of the extruded Mg-2Al-0.5Mn alloy was determined to be 1/165 that of as-cast Mg. The obtained refined alloys showed significant enhancement of yield stress and tensile strength, where the former was successfully related to the average grain size by the Hall-Petch relationship with the slope of ~ 309 MPa/µm0.5. By grain refinement, firstly the yield ratio did not change considerably while tensile strength, the work-hardening exponent, and the uniform elongation increased. However, after a transition grain size (~ 32 µm), the yield ratio increased sharply due to the large increase in the yield stress, and hence, it was not possible to further enhance the uniform elongation by grain refinement despite obtaining higher yield and tensile strengths.

Keywords


[1] S. You, Y. Huang, K.U. Kainer, N. Hort, Recent research and developments on wrought magnesium alloys, Journal of Magnesium and Alloys, 5 (2017) 239-253.
[2] H. Mirzadeh, Constitutive analysis of Mg–Al–Zn magnesium alloys during hot deformation, Mechanics of Materials, 77 (2014) 80-85.
[3] H. Mirzadeh, M. Roostaei, M.H. Parsa, R. Mahmudi, Rate controlling mechanisms during hot deformation of Mg–3Gd–1Zn magnesium alloy: Dislocation glide and climb, dynamic recrystallization, and mechanical twinning, Materials and Design, 68 (2015) 228-231.
[4] M.A. Easton, M. Qian, A. Prasad, D.H. StJohn, Recent advances in grain refinement of light metals and alloys, Current Opinion in Solid State and Materials Science, 20 (2016) 13-24.
[5] B. Pourbahari, H. Mirzadeh, M. Emamy, Toward unraveling the effects of intermetallic compounds on the microstructure and mechanical properties of Mg–Gd–Al–Zn magnesium alloys in the as-cast, homogenized, and extruded conditions, Materials Science and Engineering, A 680 (2017) 39-46.
[6] Y. Ali, D. Qiu, B. Jiang, F. Pan, M.X. Zhang, Current research progress in grain refinement of cast magnesium alloys: a review article, Journal of Alloys and Compounds, 619 (2015) 639-651.
[7] H. Yu, Y. Xin, M. Wang, Q. Liu, Hall-Petch relationship in Mg alloys: A review, Journal of Materials Science and Technology, 34 (2018) 248-256.
[8] M. Kawasaki, R.B. Figueiredo, T.G. Langdon, The Requirements for Superplasticity with an Emphasis on Magnesium Alloys, Advanced Engineering Materials, 18 (2016) 127-131.
[9] R. Alizadeh, R. Mahmudi, P.H.R. Pereira, Y. Huang, T.G. Langdon, Microstructural evolution and superplasticity in an Mg–Gd–Y–Zr alloy after processing by different SPD techniques, Materials Science and Engineering, A 682 (2017) 577-585.
[10] R. Zheng, T. Bhattacharjee, A. Shibata, T. Sasaki, K. Hono, M. Joshi, N. Tsuji, Simultaneously enhanced strength and ductility of Mg-Zn-Zr-Ca alloy with fully recrystallized ultrafine grained structures, Scripta Materialia, 131 (2017) 1-5.
[11] M. Sarebanzadeh, R. Roumina, R. Mahmudi, G.H. Wu, H.R. Jafari Nodooshan, Enhancement of superplasticity in a fine-grained Mg–3Gd–1Zn alloy processed by equal-channel angular pressing, Materials Science and Engineering, A 646 (2015) 249-253.
[12] N. Bayat Tork, S.H. Razavi, H. Saghafian, R. Mahmudi, Superplasticity of a fine-grained Mg–1.5 wt% Gd alloy after severe plastic deformation, Iranian Journal of Materials Forming, 3 (2016) 65-74.
[13] E. Bagherpour, M. Reihanian, N. Pardis, R. Ebrahimi, T.G. Langdon, Ten Years of Severe Plastic Deformation (SPD) in Iran, part I: Equal-Channel Angular Pressing (ECAP), Iranian Journal of Materials Forming, 5 (2018) 71-113.
[14] B.P. Zhang, L. Geng, L.J. Huang, X.X. Zhang, C.C. Dong, Enhanced mechanical properties in fine-grained Mg–1.0 Zn–0.5 Ca alloys prepared by extrusion at different temperatures, Scripta Materialia, 63 (2010) 1024-1027.
[15] B. Pourbahari, H. Mirzadeh, M. Emamy, The effects of grain refinement and rare earth intermetallics on mechanical properties of as-cast and wrought magnesium alloys, Journal of Materials Engineering and Performance, 27 (2018) 1327-1333.
[16] A. Kumar, G.K. Meenashisundaram, V. Manakari, G. Parande, M. Gupta, Lanthanum effect on improving CTE, damping, hardness and tensile response of Mg-3Al alloy, Journal of Alloys and Compounds, 695 (2017) 3612-3620.
[17] J. Walker, S. Shadanbaz, T.B.F. Woodfield, M.P. Staiger, G.J. Dias, Magnesium biomaterials for orthopedic application: a review from a biological perspective, Journal of Biomedical Materials Research Part B: Applied Biomaterials 102 (2014) 1316-1331.
[18] S. Candan, E. Candan, Comparative study on corrosion behaviors of Mg-Al-Zn alloys, Transactions of Nonferrous Metals Society of China 28 (2018) 642-650.
[19] H. Feng, S. Liu, Y. Du, T. Lei, R. Zeng, T. Yuan, Effect of the second phases on corrosion behavior of the Mg-Al-Zn alloys, Journal of Alloys and Compounds, 695 (2017) 2330-2338.
[20] D.H. StJohn, M.A. Qian, M.A. Easton, P. Cao, Z. Hildebrand, Grain refinement of magnesium alloys, Metallurgical and Materials Transactions, A 36 (2005) 1669-1679.
[21] Y.N. Wang, C.I. Chang, C.J. Lee, H.K. Lin, J.C. Huang, Texture and weak grain size dependence in friction stir processed Mg–Al–Zn alloy, Scripta Materialia 55 (2006) 637-640.
[22] L. Guo, Z. Chen, L. Gao, Effects of grain size, texture and twinning on mechanical properties and work-hardening behavior of AZ31 magnesium alloys, Materials Science and Engineering, A 528 (2011) 8537-8545.
[23] Y. Chino, M. Mabuchi, R. Kishihara, H. Hosokawa, Y. Yamada, C. Wen, Apos, K. Shimojima, H. Iwasaki, Mechanical properties and press formability at room temperature of AZ31 Mg alloy processed by single roller drive rolling, Materials Transactions, 43 (2002) 2554-2560. 
 [24] Y. Wang, H. Choo, Influence of texture on Hall–Petch relationships in an Mg alloy, Acta Materialia, 81 (2014) 83-97.
[25] R. Kuziak, R. Kawalla, S. Waengler, Advanced high strength steels for automotive industry, Archives of Civil and Mechanical Engineering 8 (2008) 103-116.
[26] M. Nouroozi, H. Mirzadeh, M. Zamani, Effect of microstructural refinement and intercritical annealing time on mechanical properties of high-formability dual phase steel, Materials Science and Engineering, A 736 (2018) 22-26
[27] G.E. Dieter, Mechanical Metallurgy, 3rd ed., McGraw-Hill, (1988).